The help file (Press the ? at the top of the BI5 screen and search for IPv6) states that IPv6 WAN addresses will work. Have you read the section "Remote Access Wizard" ? Probably best to do that first before going any further, then you can ask questions if you get stuck.
Random thoughts:
1. I agree, WhatsmyIP is a good way to find your WAN address.
2. What address is BI5 settings/Web Server/ WAN actually showing ? (Don't give us the full address as somebody may try to connect to it). Is it IPv4 or IPv6 ? Does it match WhatsmyIP ? Refresh WhatsmyIP to be sure you are looking at your IP address.
3. The help file states that IPv6 addresses MUST be in square brackets, for example (from the help file):
http://[2604:9108:80e:5223:8877:cc6f
4. Maybe the phone app can only auto populate with ipv4 addresses.
5. For external comms, you do need to sort out port forwarding in your modem router, but as mentioned before it is not a good thing to be opening ports security wise. You basically point your chosen port to the BI5 pc's static IP address, so anything coming in externally on that port will be forwarded to BI5.
6. You can then test if it works by turning off wifi on your mobile phone and starting BI5 using phone data.
7. If it does work, it will fail when your ISP changes your WAN address. Next job !